Novel Artificial Material Could Facilitate Wireless Power

This advance is made possible by the recent ability to fabricate exotic composite materials known as metamaterials, which are not so much a single substance, but an entire human-made structure that can be engineered to exhibit properties not readily found in nature. In fact, the metamaterial used in earlier Duke studies, and which would likely be used in future wireless power transmission systems, resembles a miniature set of tan Venetian blinds.

Theoretically, this metamaterial can improve the efficiency of"recharging" devices without wires. As power passes from the transmitting device to the receiving device, most if not all of it scatters and dissipates unless the two devices are extremely close together. However, the metamaterial postulated by the Duke researchers, which would be situated between the energy source and the"recipient" device, greatly refocuses the energy transmitted and permits the energy to traverse the open space between with minimal loss of power.

"We currently have the ability to transmit small amounts of power over short distances, such as in radio frequency identification (RFID) devices," said Yaroslav Urzhumov, assistant research professor in electrical and computer engineering at Duke's Pratt School of Engineering."However, larger amounts of energy, such as that seen in lasers or microwaves, would burn up anything in its path.

"Based on our calculations, it should be possible to use these novel metamaterials to increase the amount of power transmitted without the negative effects," Urzhumov said.

The results of the Duke research were published online in the journalPhysical Review B. Urzhumov works in the laboratory of David R. Smith, William Bevan Professor of electrical and computer engineering at Pratt School of Engineering. Smith's team was the first demonstrate that similar metamaterials could act as a cloaking device in 2006.

Just as the metamaterial in the cloaking device appeared to make a volume of space"disappear," in the latest work, the metamaterial would make it seem as if there was no space between the transmitter and the recipient, Urzhumov said. Therefore, he said, the loss of power should be minimal.

Urzhumov's research is an offshoot of"superlens" research conducted in Smith's laboratory. Traditional lenses get their focusing power by controlling rays as they pass through the two outside surfaces of the lens. On the other hand, the superlens, which is in fact a metamaterial, directs waves within the bulk of the lens between the outside surfaces, giving researchers a much greater control over whatever passes through it.

The metamaterial used in wireless power transmission would likely be made of hundreds to thousands -- depending on the application -- of individual thin conducting loops arranged into an array. Each piece is made from the same copper-on-fiberglass substrate used in printed circuit boards, with excess copper etched away. These pieces can then be arranged in an almost infinite variety of configurations.

"The system would need to be tailored to the specific recipient device, in essence the source and target would need to be 'tuned' to each other," Urzhumov said."This new understanding of how matematerials can be fabricated and arranged should help make the design of wireless power transmission systems more focused."

The analysis performed at Duke was inspired by recent studies at Mitsubishi Electric Research Labs (MERL), an industrial partner of the Duke Center for Metamaterials and Integrated Plasmonics. MERL is currently investigating metamaterials for wireless power transfer. The Duke researchers said that with these new insights into the effects of metamaterials, developing actual devices can be more targeted and efficient.

The Duke University research was supported by a Multidisciplinary University Research Initiative (MURI) grant through the Air Force Office of Scientific Research and the U.S. Army Research Office.

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Exploring the Superconducting Transition in Ultra Thin Films

"Understanding exactly what happens when a normally insulating copper-oxide material transitions from the insulating to the superconducting state is one of the great mysteries of modern physics," said Brookhaven physicist Ivan Bozovic, lead author on the study.

One way to explore the transition is to apply an external electric field to increase or decrease the level of"doping" -- that is, the concentration of mobile electrons in the material -- and see how this affects the ability of the material to carry current. But to do this in copper-oxide (cuprate) superconductors, one needs extremely thin films of perfectly uniform composition -- and electric fields measuring more than 10 billion volts per meter. (For comparison, the electric field directly under a power transmission line is 10 thousand volts per meter.)

Bozovic's group has employed a technique called molecular beam epitaxy (MBE) to uniquely create such perfect superconducting thin films one atomic layer at a time, with precise control of each layer's thickness. Recently, they've shown that in such MBE-created films even a single cuprate layer can exhibit undiminished high-temperature superconductivity.

Now, they've applied the same technique to build ultrathin superconducting field effect devices that allow them to achieve the charge separation, and thus electric field strength, for these critical studies.

These devices are similar to the field-effect transistors (FETs) that are the basis of all modern electronics, in which a semiconducting material transports electrical current from the"source" electrode on one end of the device to a"drain" electrode on the other end. FETs are controlled by a third electrode, called a"gate," positioned above the source-drain channel -- separated by a thin insulator -- which switches the device on or off when a particular gate voltage is applied to it.

But because no known insulator could withstand the high fields required to induce superconductivity in the cuprates, the standard FET scheme doesn't work for high-temperature superconductor FETs. Instead, the scientists used electrolytes, liquids that conduct electricity, to separate the charges.

In this setup, when an external voltage is applied, the electrolyte's positively charged ions travel to the negative electrode and the negatively charged ions travel to the positive electrode. But when the ions reach the electrodes, they abruptly stop, as though they've hit a brick wall. The electrode"walls" carry an equal amount of opposite charge, and the electric field between these two oppositely charged layers can exceed the 10 billion volts per meter goal.

The result is a field effect device in which the critical temperature of a prototype high-temperature superconductor compound (lanthanum-strontium-copper-oxide) can be tuned by as much as 30 degrees Kelvin, which is about 80 percent of its maximal value -- almost ten times more than the previous record.

The scientists have now used this enhanced device to study some of the basic physics of high-temperature superconductivity.

One key finding: As the density of mobile charge carriers is increased, their cuprate film transitions from insulating to superconducting behavior when the film sheet resistance reaches 6.45 kilo-ohm. This is exactly equal to the Planck quantum constant divided by twice the electron charge squared -- h/(2e)². Both the Planck constant and electron charge are"atomic" units -- the minimum possible quantum of action and of electric charge, respectively, established after the advent of quantum mechanics early in the last century.

"It is striking to see a signature of such clearly quantum-mechanical behavior in a macroscopic sample (up to millimeter scale) and at a relatively high temperature," Bozovic said. Most people associate quantum mechanics with characteristic behavior of atoms and molecules.

This result also carries another surprising message. While it has been known for many years that electrons are paired in the superconducting state, the findings imply that they also form pairs (although localized and immobile) in the insulating state, unlike in any other known material. That sets the scientists on a more focused search for what gets these immobilized pairs moving when the transition to superconductivity occurs.

Superconducting FETs might also have direct practical applications. Semiconductor-based FETs are power-hungry, particularly when packed very densely to increase their speed. In contrast, superconductors operate with no resistance or energy loss. Here, the atomically thin layer construction is in fact advantageous -- it enhances the ability to control superconductivity using an external electric field.

"This is just the beginning," Bozovic said."We still have so much to learn about high-temperature superconductors. But as we continue to explore these mysteries, we are also striving to make ultrafast and power-saving superconducting electronics a reality."

This research was funded by the DOE Office of Science and the Swiss National Science Foundation.

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New Solar Cell Technology Greatly Boosts Efficiency

The technology substantially overcomes the problem of poor transport of charges generated by solar photons. These charges -- negative electrons and positive holes -- typically become trapped by defects in bulk materials and their interfaces and degrade performance.

"To solve the entrapment problems that reduce solar cell efficiency, we created a nanocone-based solar cell, invented methods to synthesize these cells and demonstrated improved charge collection efficiency," said Xu, a member of ORNL's Chemical Sciences Division.

The new solar structure consists of n-type nanocones surrounded by a p-type semiconductor. The n-type nanoncones are made of zinc oxide and serve as the junction framework and the electron conductor. The p-type matrix is made of polycrystalline cadmium telluride and serves as the primary photon absorber medium and hole conductor.

With this approach at the laboratory scale, Xu and colleagues were able to obtain a light-to-power conversion efficiency of 3.2 percent compared to 1.8 percent efficiency of conventional planar structure of the same materials.

"We designed the three-dimensional structure to provide an intrinsic electric field distribution that promotes efficient charge transport and high efficiency in converting energy from sunlight into electricity," Xu said.

Key features of the solar material include its unique electric field distribution that achieves efficient charge transport; the synthesis of nanocones using inexpensive proprietary methods; and the minimization of defects and voids in semiconductors. The latter provides enhanced electric and optical properties for conversion of solar photons to electricity.

Because of efficient charge transport, the new solar cell can tolerate defective materials and reduce cost in fabricating next-generation solar cells.

"The important concept behind our invention is that the nanocone shape generates a high electric field in the vicinity of the tip junction, effectively separating, injecting and collecting minority carriers, resulting in a higher efficiency than that of a conventional planar cell made with the same materials," Xu said.

Research that forms the foundation of this technology was accepted by this year's Institute of Electrical and Electronics Engineers photovoltaic specialist conference and will be published in the IEEE Proceedings. The papers are titled"Efficient Charge Transport in Nanocone Tip-Film Solar Cells" and"Nanojunction solar cells based on polycrystalline CdTe films grown on ZnO nanocones."

The research was supported by the Laboratory Directed Research and Development program and the Department of Energy's Office of Nonproliferation Research and Engineering.

Other contributors to this technology are Sang Hyun Lee, X-G Zhang, Chad Parish, Barton Smith, Yongning He, Chad Duty and Ho Nyung Lee.

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Toward Optical Computing in Handheld Electronics: Graphene Optical Modulators Could Lead to Ultrafast Communications

The team of researchers, led by UC Berkeley engineering professor Xiang Zhang, built a tiny optical device that uses graphene, a one-atom-thick layer of crystallized carbon, to switch light on and off. This switching ability is the fundamental characteristic of a network modulator, which controls the speed at which data packets are transmitted. The faster the data pulses are sent out, the greater the volume of information that can be sent. Graphene-based modulators could soon allow consumers to stream full-length, high-definition, 3-D movies onto a smartphone in a matter of seconds, the researchers said.

"This is the world's smallest optical modulator, and the modulator in data communications is the heart of speed control," said Zhang, who directs a National Science Foundation (NSF) Nanoscale Science and Engineering Center at UC Berkeley."Graphene enables us to make modulators that are incredibly compact and that potentially perform at speeds up to ten times faster than current technology allows. This new technology will significantly enhance our capabilities in ultrafast optical communication and computing."

In this latest work, described in the May 8 advanced online publication of the journalNature, researchers were able to tune the graphene electrically to absorb light in wavelengths used in data communication. This advance adds yet another advantage to graphene, which has gained a reputation as a wonder material since 2004 when it was first extracted from graphite, the same element in pencil lead. That achievement earned University of Manchester scientists Andre Geim and Konstantin Novoselov the Nobel Prize in Physics last year.

Zhang worked with fellow faculty member Feng Wang, an assistant professor of physics and head of the Ultrafast Nano-Optics Group at UC Berkeley. Both Zhang and Wang are faculty scientists at Lawrence Berkeley National Laboratory's Materials Science Division.

"The impact of this technology will be far-reaching," said Wang."In addition to high-speed operations, graphene-based modulators could lead to unconventional applications due to graphene's flexibility and ease in integration with different kinds of materials. Graphene can also be used to modulate new frequency ranges, such as mid-infrared light, that are widely used in molecular sensing."

Graphene is the thinnest, strongest crystalline material yet known. It can be stretched like rubber, and it has the added benefit of being an excellent conductor of heat and electricity. This last quality of graphene makes it a particularly attractive material for electronics.

"Graphene is compatible with silicon technology and is very cheap to make," said Ming Liu, post-doctoral researcher in Zhang's lab and co-lead author of the study."Researchers in Korea last year have already produced 30-inch sheets of it. Moreover, very little graphene is required for use as a modulator. The graphite in a pencil can provide enough graphene to fabricate 1 billion optical modulators."

It is the behavior of photons and electrons in graphene that first caught the attention of the UC Berkeley researchers.

The researchers found that the energy of the electrons, referred to as its Fermi level, can be easily altered depending upon the voltage applied to the material. The graphene's Fermi level in turn determines if the light is absorbed or not.

When a sufficient negative voltage is applied, electrons are drawn out of the graphene and are no longer available to absorb photons. The light is"switched on" because the graphene becomes totally transparent as the photons pass through.

Graphene is also transparent at certain positive voltages because, in that situation, the electrons become packed so tightly that they cannot absorb the photons.

The researchers found a sweet spot in the middle where there is just enough voltage applied so the electrons can prevent the photons from passing, effectively switching the light"off."

"If graphene were a hallway, and electrons were people, you could say that, when the hall is empty, there's no one around to stop the photons," said Xiaobo Yin, co-lead author of the Nature paper and a research scientist in Zhang's lab."In the other extreme, when the hall is too crowded, people can't move and are ineffective in blocking the photons. It's in between these two scenarios that the electrons are allowed to interact with and absorb the photons, and the graphene becomes opaque."

In their experiment, the researchers layered graphene on top of a silicon waveguide to fabricate optical modulators. The researchers were able to achieve a modulation speed of 1 gigahertz, but they noted that the speed could theoretically reach as high as 500 gigahertz for a single modulator.

While components based upon optics have many advantages over those that use electricity, including the ability to carry denser packets of data more quickly, attempts to create optical interconnects that fit neatly onto a computer chip have been hampered by the relatively large amount of space required in photonics.

Light waves are less agile in tight spaces than their electrical counterparts, the researchers noted, so photon-based applications have been primarily confined to large-scale devices, such as fiber optic lines.

"Electrons can easily make an L-shaped turn because the wavelengths in which they operate are small," said Zhang."Light wavelengths are generally bigger, so they need more space to maneuver. It's like turning a long, stretch limo instead of a motorcycle around a corner. That's why optics require bulky mirrors to control their movements. Scaling down the optical device also makes it faster because the single atomic layer of graphene can significantly reduce the capacitance -- the ability to hold an electric charge -- which often hinders device speed."

Graphene-based modulators could overcome the space barrier of optical devices, the researchers said. They successfully shrunk a graphene-based optical modulator down to a relatively tiny 25 square microns, a size roughly 400 times smaller than a human hair. The footprint of a typical commercial modulator can be as large as a few square millimeters.

Even at such a small size, graphene packs a punch in bandwidth capability. Graphene can absorb a broad spectrum of light, ranging over thousands of nanometers from ultraviolet to infrared wavelengths. This allows graphene to carry more data than current state-of-the-art modulators, which operate at a bandwidth of up to 10 nanometers, the researchers said.

"Graphene-based modulators not only offer an increase in modulation speed, they can enable greater amounts of data packed into each pulse," said Zhang."Instead of broadband, we will have 'extremeband.' What we see here and going forward with graphene-based modulators are tremendous improvements, not only in consumer electronics, but in any field that is now limited by data transmission speeds, including bioinformatics and weather forecasting. We hope to see industrial applications of this new device in the next few years."

Other UC Berkeley co-authors of this paper are graduate student Erick Ulin-Avila and post-doctoral researcher Thomas Zentgraf in Zhang's lab; and visiting scholar Baisong Geng and graduate student Long Ju in Wang's lab.

This work was supported through the Center for Scalable and Integrated Nano-Manufacturing (SINAM), an NSF Nanoscale Science and Engineering Center. Funding from the Department of Energy's Basic Energy Science program at Lawrence Berkeley National Laboratory also helped support this research.

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Scientists Achieve Guiding of Electrons by Purely Electric Fields

The research is published online inPhysical Review Letters.

This new technique of electron guiding -- which resembles the guiding of light waves in optical fibres -- promises a variety of applications, from guided matter-wave experiments to non-invasive electron microscopy.

Electrons have been the first elementary particles revealing their wave-like properties and have therefore been of great importance in the development of the theory of quantum mechanics. Even now the observation of electrons leads to new insight into the fundamental laws of physics. Measurements involving confined electrons have so far mainly been performed in so-called Penning traps, which combine a static magnetic field with an oscillating electric field.

For a number of experiments with propagating electrons, like interferometry with slow electrons, it would be advantageous to confine the electrons by a purely electric field. This can be done in an alternating quadrupole potential similar to the standard technique that is used for ion trapping. These so-called Paul traps are based on four electrodes to which a radiofrequency voltage is applied. The resulting field evokes a driving force which keeps the particle in the centre of the trap. Wolfgang Paul received the Nobel Prize in physics for the invention of these traps in 1989.

For several years by now scientists realize Paul traps with micro structured electrodes on planar substrates, using standard microelectronic chip technology. Dr. Hommelhoff and his group have now applied this method for the first time to electrons. Since the mass of these point-like particles is only a tenth of a thousandth of the mass of an ion, electrons react much faster to electric fields than the rather heavy ions. Hence, in order to guide electrons, the frequency of the alternating voltage applied to the electrodes has to be much higher than for the confinement of ions and is in the microwave range, at around 1 GHz.

In the experiment electrons are generated in a thermal source (in which a tungsten wire is heated like in a light bulb) and the emitted electrons are collimated to a parallel beam of a few electron volts. From there the electrons are injected into the"wave-guide." It is being generated by five electrodes on a planar substrate to which an alternating voltage with a frequency of about 1 GHz is applied. This introduces an oscillating quadrupole field in a distance of half a millimetre above the electrodes, which confines the electrons in the radial direction. In the longitudinal direction there is no force acting on the particles so that they are free to travel along the"guide tube." As the confinement in the radial direction is very strong the electrons are forced to follow even small directional changes of the electrodes.

In order to make this effect more visible the 37mm long electrodes are bent to a curve of 30 degrees opening angle and with a bending radius of 40mm. At the end of the structure the guided electrons are ejected and registered by a detector. A bright spot caused by guided electrons appears on the detector right at the exit of the guide tube, which is situated in the left part of the picture. When the alternating field is switched off a more diffusively illuminated area shows up on the right side. It is caused by electrons spreading out from the source and propagating on straight trajectories over the substrate.

"With this fundamental experiment we were able to show that electrons can be efficiently guided be purely electric fields," says Dr. Hommelhoff."However, as our electron source yields a rather poorly collimated electron beam we still lose many electrons." In the future the researchers plan to combine the new microwave guide with an electron source based on field emission from an atomically sharp metal tip. These devices deliver electron beams with such a strong collimation that their transverse component is limited by the Heisenberg uncertainty principle only.

Under these conditions it should be feasible to investigate the individual quantum mechanical oscillations of the electrons in the radial potential of the guide."The strong confinement of electrons observed in our experiment means that a"jump" from one quantum state to the neighbouring higher state requires a lot of energy and is therefore not very likely to happen," explains Johannes Hoffrogge, doctoral student at the experiment."Once a single quantum state is populated it will remain so for an extended period of time and can be used for quantum experiments." This would make it possible to conduct quantum physics experiments such as interferometry with guided slow electrons. Here the wave function of an electron is first split up; later on, its two components are brought together again whereby characteristic superpositions of quantum states of the electron can be generated. But the new method could also be applied for a new form of electron microscopy.

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What Electric Car Convenience Is Worth

Results of one study show the electric car attributes that are most important for consumers: driving range, fuel cost savings and charging time. The results are based on a national survey conducted by the researchers, UD professors George Parsons, Willett Kempton and Meryl Gardner, and Michael Hidrue, who recently graduated from UD with a doctoral degree in economics. Lead author Hidrue conducted the research for his dissertation.

The study, which surveyed more than 3,000 people, showed what individuals would be willing to pay for various electric vehicle attributes. For example, as battery charging time decreases from 10 hours to five hours for a 50-mile charge, consumers' willingness to pay is about$427 per hour in reduction time. Drop charging time from five hours to one hour, and consumers would pay an estimated$930 an hour. Decrease the time from one hour to 10 minutes, and they would pay$3,250 per hour.

For driving range, consumers value each additional mile of range at about$75 per mile up to 200 miles, and$35 a mile from 200-300 miles. So, for example, if an electric vehicle has a range of 200 miles and an otherwise equivalent gasoline vehicle has a range of 300, people would require a price discount of about$3,500 for the electric version. That assumes everything else about the vehicle is the same, and clearly there is lower fuel cost with an electric vehicle and often better performance. So all the attributes have to be accounted for in the final analysis of any car.

"This information tells the car manufacturers what people are willing to pay for another unit of distance," Parsons said."It gives them guidance as to what cost levels they need to attain to make the cars competitive in the market."

The researchers found that battery costs would need to decrease substantially without subsidy and with current gas prices for electric cars to become competitive in the market. However, the researchers said, the current$7,500 government tax credit could bridge the gap between electric car costs and consumers' willingness to pay if battery costs decline to$300 a kilowatt hour, the projected 2014 cost level by the Department of Energy. Many analysts believe that goal is within reach.

The team's analysis could also help guide automakers' marketing efforts -- it showed that an individual's likelihood of buying an electric vehicle increases with characteristics such as youth, education and an environmental lifestyle. Income was not important.

In a second recently published study, UD researchers looked at electric vehicle driving range using second-by-second driving records. That study, which is based on a year of driving data from nearly 500 instrumented gasoline vehicles, showed that 9 percent of the vehicles never exceeded 100 miles in a day. For those who are willing to make adaptations six times a year -- borrow a gasoline car, for example -- the 100-mile range would work for 32 percent of drivers.

"It appears that even modest electric vehicles with today's limited battery range, if marketed correctly to segments with appropriate driving behavior, comprise a large enough market for substantial vehicle sales," the authors concluded.

Kempton, who published the driving patterns article with UD marine policy graduate student Nathaniel Pearre and colleagues at the Georgia Institute of Technology, pointed out that U.S. car sales are around 12 million in an average, non-recession year. Nine percent of that would be a million cars per year -- for comparison to current production, for example, Chevy plans to manufacture just 10,000 Volts in 2011.

By this measure, the potential market would justify many more plug-in cars than are currently being produced, Kempton said.

The findings of the two studies were reported online in March and February inResource and Energy EconomicsandTransportation Research, respectively.

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Pairing Quantum Dots With Fullerenes for Nanoscale Photovoltaics

"This is the first demonstration of a hybrid inorganic/organic, dimeric (two-particle) material that acts as an electron donor-bridge-acceptor system for converting light to electrical current," said Brookhaven physical chemist Mircea Cotlet, lead author of a paper describing the dimers and their assembly method inAngewandte Chemie.

By varying the length of the linker molecules and the size of the quantum dots, the scientists can control the rate and the magnitude of fluctuations in light-induced electron transfer at the level of the individual dimer."This control makes these dimers promising power-generating units for molecular electronics or more efficient photovoltaic solar cells," said Cotlet, who conducted this research with materials scientist Zhihua Xu at Brookhaven's Center for Functional Nanomaterials (CFN).

Scientists seeking to develop molecular electronics have been very interested in organic donor-bridge-acceptor systems because they have a wide range of charge transport mechanisms and because their charge-transfer properties can be controlled by varying their chemistry. Recently, quantum dots have been combined with electron-accepting materials such as dyes, fullerenes, and titanium oxide to produce dye-sensitized and hybrid solar cells in the hope that the light-absorbing and size-dependent emission properties of quantum dots would boost the efficiency of such devices. But so far, the power conversion rates of these systems have remained quite low.

"Efforts to understand the processes involved so as to engineer improved systems have generally looked at averaged behavior in blended or layer-by-layer structures rather than the response of individual, well-controlled hybrid donor-acceptor architectures," said Xu.

The precision fabrication method developed by the Brookhaven scientists allows them to carefully control particle size and interparticle distance so they can explore conditions for light-induced electron transfer between individual quantum dots and electron-accepting fullerenes at the single molecule level.

The entire assembly process takes place on a surface and in a stepwise fashion to limit the interactions of the components (particles), which could otherwise combine in a number of ways if assembled by solution-based methods. This surface-based assembly also achieves controlled, one-to-one nanoparticle pairing.

To identify the optimal architectural arrangement for the particles, the scientists strategically varied the size of the quantum dots -- which absorb and emit light at different frequencies according to their size -- and the length of the bridge molecules connecting the nanoparticles. For each arrangement, they measured the electron transfer rate using single molecule spectroscopy.

"This method removes ensemble averaging and reveals a system's heterogeneity -- for example fluctuating electron transfer rates -- which is something that conventional spectroscopic methods cannot always do," Cotlet said.

The scientists found that reducing quantum dot size and the length of the linker molecules led to enhancements in the electron transfer rate and suppression of electron transfer fluctuations.

"This suppression of electron transfer fluctuation in dimers with smaller quantum dot size leads to a stable charge generation rate, which can have a positive impact on the application of these dimers in molecular electronics, including potentially in miniature and large-area photovoltaics," Cotlet said.

"Studying the charge separation and recombination processes in these simplified and well-controlled dimer structures helps us to understand the more complicated photon-to-electron conversion processes in large-area solar cells, and eventually improve their photovoltaic efficiency," Xu added.

A U.S. patent application is pending on the method and the materials resulting from using the technique, and the technology is available for licensing. This work was funded by the DOE Office of Science.

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